One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,8,4)(9,10)(11,13)(12,16)(14,15)(17,18,22,21)(19,24,20,23)(25,26)(27,32)(28,30)(29,31)(10,15)(13,16)(17,19,22,20)(18,23,21,24)(25,26,29,31)(27,32,28,30)(2,6)(4,7)(9,11,14,12)(10,13,15,16)(17,19,22,20)(18,23,21,24)(25,27,29,28)(26,30,31,32)(1,3)(2,4)(5,8)(6,7)(9,12,14,11)(10,16,15,13)(17,20,22,19)(18,23,21,24)(25,28,29,27)(26,30,31,32)(1,4)(2,3)(5,7)(6,8)(9,13,14,16)(10,11,15,12)(17,21,22,18)(19,23,20,24)(25,26)(27,32)(28,30)(29,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.