One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,13,8,14,7,12)(3,15,18,9,20,34,19,35)(4,21,25,10,26,38,24,39)(5,27,29,11,31,41,30,42)(16,32,22,36,47,61,46,43)(17,33,28,44,49,57,48,40)(23,52,55,58,56,37,54,50)(45,63,59,64,53,62,51,60)(1,3,6,18,8,20,7,19)(2,9,12,15,14,35,13,34)(4,22,24,16,26,46,25,47)(5,28,29,49,31,48,30,17)(10,36,38,61,39,43,21,32)(11,40,27,57,42,44,41,33)(23,53,54,59,56,45,55,51)(37,60,50,63,52,64,58,62)(1,4)(2,10)(3,16,20,47)(5,23)(6,25)(7,24)(8,26)(9,32,35,61)(11,37)(12,21)(13,38)(14,39)(15,43,34,36)(17,45,49,53)(18,22,19,46)(27,58)(28,59,48,51)(29,55)(30,54)(31,56)(33,60,57,64)(40,62,44,63)(41,50)(42,52)(1,5,8,31)(2,11,14,42)(3,17,20,49)(4,23,26,56)(6,30,7,29)(9,33,35,57)(10,37,39,52)(12,41,13,27)(15,44,34,40)(16,45,47,53)(18,48,19,28)(21,50,38,58)(22,51,46,59)(24,55,25,54)(32,60,61,64)(36,62,43,63)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.