One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,8,13,6,12,7,26)(3,14,17,32,18,9,28,41)(4,10,27,36,21,35,22,39)(5,23,29,52,24,11,25,38)(15,30,19,47,43,40,46,33)(16,37,44,56,45,31,54,61)(20,49,53,62,50,34,51,59)(42,55,48,58,63,60,64,57)(1,3,7,17,6,18,8,28)(2,9,26,41,12,14,13,32)(4,19,22,43,21,46,27,15)(5,16,25,44,24,45,29,54)(10,33,39,30,35,47,36,40)(11,37,52,56,23,31,38,61)(20,48,51,63,50,64,53,42)(34,58,62,60,49,57,59,55)(1,4,6,21)(2,10,12,35)(3,15,18,43)(5,20,24,50)(7,27,8,22)(9,30,14,40)(11,34,23,49)(13,39,26,36)(16,42,45,63)(17,46,28,19)(25,53,29,51)(31,55,37,60)(32,47,41,33)(38,62,52,59)(44,64,54,48)(56,58,61,57)(1,5)(2,11,12,23)(3,16)(4,20)(6,24)(7,25)(8,29)(9,31,14,37)(10,34,35,49)(13,38,26,52)(15,42)(17,44)(18,45)(19,48)(21,50)(22,51)(27,53)(28,54)(30,55,40,60)(32,56,41,61)(33,57,47,58)(36,59,39,62)(43,63)(46,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.