One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,7,13,8,14,6,12)(3,15,19,9,20,34,18,35)(4,21,24,10,26,38,25,39)(5,27,29,11,31,41,30,42)(16,43,22,51,46,32,45,36)(17,47,28,58,49,33,48,40)(23,53,56,62,57,37,55,50)(44,63,64,61,54,60,52,59)(1,3,6,19,8,20,7,18)(2,9,12,34,14,35,13,15)(4,22,25,46,26,45,24,16)(5,28,29,17,31,48,30,49)(10,36,21,43,39,51,38,32)(11,40,41,33,42,58,27,47)(23,54,56,64,57,44,55,52)(37,61,50,63,53,59,62,60)(1,4,6,24,8,26,7,25)(2,10,12,38,14,39,13,21)(3,16,18,22,20,46,19,45)(5,23,29,55,31,57,30,56)(9,32,15,36,35,43,34,51)(11,37,41,62,42,53,27,50)(17,44,28,52,49,54,48,64)(33,59,40,60,47,61,58,63)(1,5)(2,11)(3,17,20,49)(4,23)(6,29)(7,30)(8,31)(9,33,35,47)(10,37)(12,41)(13,27)(14,42)(15,40,34,58)(16,44,46,54)(18,28,19,48)(21,50)(22,52,45,64)(24,55)(25,56)(26,57)(32,59,43,61)(36,60,51,63)(38,62)(39,53)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.