One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,13,8,12,7,14)(3,9,18,31,17,32,27,39)(4,19,28,10,22,40,21,35)(5,23,26,37,25,38,24,11)(15,41,45,29,43,56,44,33)(16,46,53,30,48,60,49,57)(20,36,51,59,52,34,54,50)(42,55,62,61,47,58,63,64)(1,3)(2,9,12,32)(4,15,22,43)(5,16)(6,27)(7,18)(8,17)(10,33)(11,30,37,57)(13,39,14,31)(19,41)(20,42,52,47)(21,45,28,44)(23,46,38,60)(24,53)(25,48)(26,49)(29,35)(34,58)(36,55)(40,56)(50,61)(51,63,54,62)(59,64)(1,4)(2,10,12,35)(3,15,17,43)(5,20)(6,21)(7,28)(8,22)(9,29)(11,36,37,34)(13,19,14,40)(16,47,48,42)(18,44,27,45)(23,50,38,59)(24,51)(25,52)(26,54)(30,55)(31,41)(32,33)(39,56)(46,61)(49,63,53,62)(57,58)(60,64)(1,5,6,24,8,25,7,26)(2,11,14,23,12,37,13,38)(3,16,27,53,17,48,18,49)(4,20,21,51,22,52,28,54)(9,30,31,46,32,57,39,60)(10,34,40,59,35,36,19,50)(15,42,45,63,43,47,44,62)(29,55,41,61,33,58,56,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.