One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,14,8,12,7,13)(3,9,19,33,17,35,18,34)(4,20,23,10,25,43,24,38)(5,26,28,41,30,42,29,11)(15,44,51,58,46,36,21,31)(16,47,27,32,49,39,50,59)(22,40,54,52,55,37,56,61)(45,63,64,60,48,57,53,62)(1,3,7,19,8,17,6,18)(2,9,14,34,12,35,13,33)(4,21,24,15,25,51,23,46)(5,27,29,49,30,50,28,16)(10,36,43,58,38,44,20,31)(11,39,26,32,41,47,42,59)(22,45,56,64,55,48,54,53)(37,57,61,60,40,63,52,62)(1,4,6,23,8,25,7,24)(2,10,13,20,12,38,14,43)(3,15,18,21,17,46,19,51)(5,22,28,54,30,55,29,56)(9,31,33,44,35,58,34,36)(11,40,42,61,41,37,26,52)(16,48,50,64,49,45,27,53)(32,57,39,62,59,63,47,60)(1,5)(2,11,12,41)(3,16,17,49)(4,22)(6,28)(7,29)(8,30)(9,32)(10,37,38,40)(13,42,14,26)(15,45,46,48)(18,50,19,27)(20,52,43,61)(21,53,51,64)(23,54)(24,56)(25,55)(31,57)(33,39)(34,47)(35,59)(36,60)(44,62)(58,63)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.