One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,13)(4,18)(5,22,25,10)(6,26)(7,12)(8,16)(9,20)(11,27)(14,38)(15,36,43,29)(17,30)(19,49,52,47)(21,48)(23,33,44,54)(24,34,58,56)(28,59)(31,51,55,64)(32,53)(35,41)(37,45)(39,62,42,63)(40,46)(50,60,57,61)(1,3,6,17,7,16,27,45)(2,8,11,30,12,13,26,37)(4,14,20,41,21,40,53,59)(5,23,24,15,25,44,58,43)(9,28,18,46,32,35,48,38)(10,33,34,29,22,54,56,36)(19,50,51,39,52,57,64,42)(31,62,47,60,55,63,49,61)(1,4,6,20,7,21,27,53)(2,9,11,18,12,32,26,48)(3,14,17,41,16,40,45,59)(5,19,24,51,25,52,58,64)(8,28,30,46,13,35,37,38)(10,31,34,47,22,55,56,49)(15,42,44,50,43,39,23,57)(29,61,54,62,36,60,33,63)(1,5)(2,10)(3,15,16,43)(4,19)(6,24)(7,25)(8,29,13,36)(9,31)(11,34)(12,22)(14,39,40,42)(17,44,45,23)(18,47)(20,51)(21,52)(26,56)(27,58)(28,60,35,61)(30,54,37,33)(32,55)(38,62,46,63)(41,57,59,50)(48,49)(53,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.