One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,6,7,8)(9,10)(11,15)(12,13)(14,16)(18,20)(19,23)(25,26)(27,29)(28,30)(31,32)(2,4)(3,7)(9,10)(11,15)(12,13)(14,16)(17,18,21,20)(19,24,23,22)(27,31)(29,32)(2,4)(6,8)(10,13)(14,15)(18,20)(19,23)(25,26,28,30)(27,29,31,32)(1,3,5,7)(2,6,4,8)(9,10)(11,14)(12,13)(15,16)(17,19,21,23)(18,22,20,24)(25,26)(27,29)(28,30)(31,32)(1,4,5,2)(3,8,7,6)(9,11)(10,14)(12,16)(13,15)(17,20,21,18)(19,24,23,22)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.