One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,15,20,35)(4,21)(5,12)(6,10)(7,13)(8,14)(9,18,37,28)(11,23)(16,36,30,33)(17,34,50,60)(19,44,51,59)(22,39,48,61)(24,53)(25,42)(26,40)(27,43)(29,38)(31,57)(32,45)(41,54)(46,55)(47,64,56,63)(49,58,52,62)(1,3,6,28,8,20,5,18)(2,9,12,15,14,37,10,35)(4,22,23,50,26,48,25,17)(7,30,29,19,32,16,27,51)(11,39,21,34,42,61,40,60)(13,44,43,33,45,59,38,36)(24,52,54,56,31,49,55,47)(41,62,53,64,46,58,57,63)(2,10)(3,16,20,30)(5,6)(7,29)(9,33,37,36)(11,21)(12,14)(13,45)(15,44,35,59)(17,47,50,56)(18,51,28,19)(22,49,48,52)(23,25)(24,55)(27,32)(31,54)(34,58,60,62)(39,63,61,64)(40,42)(41,46)(1,4,8,26)(2,11,14,42)(3,17)(5,23,6,25)(7,31,32,24)(9,34)(10,21,12,40)(13,46,45,41)(15,39)(16,47)(18,22)(19,52)(20,50)(27,55,29,54)(28,48)(30,56)(33,58)(35,61)(36,62)(37,60)(38,57,43,53)(44,63)(49,51)(59,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.