One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,5)(4,6)(7,8)(9,10,12,14)(11,13,15,16)(17,18)(19,24)(20,21)(22,23)(25,26)(27,31)(28,30)(29,32)(4,8)(6,7)(17,19)(18,21)(20,22)(23,24)(25,26)(27,31)(28,30)(29,32) involution — undirected(2,3)(6,7)(19,20)(21,24)(25,26,28,30)(27,29,32,31)(1,3,5,2)(4,7,8,6)(9,10)(11,13)(12,14)(15,16)(17,20,22,19)(18,21,23,24)(25,26)(27,29)(28,30)(31,32)(1,4)(2,6)(3,7)(5,8)(9,11,12,15)(10,13,14,16)(17,21)(18,19)(20,23)(22,24)(25,27,28,32)(26,29,30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.