One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,8)(3,4,5,7)(9,10,15,16)(11,12,14,13)(19,23)(22,24)(27,28)(31,32)(1,3,6,5)(2,7,8,4)(9,11)(10,13)(12,16)(14,15)(18,21)(22,24)(26,30)(31,32)(3,5)(4,7)(9,12,15,13)(10,11,16,14)(17,18,20,21)(19,22,23,24)(25,26)(27,31)(28,32)(29,30)(1,4,6,7)(2,3,8,5)(9,13,15,12)(10,11,16,14)(25,27,29,28)(26,31,30,32)(1,5,6,3)(2,7,8,4)(9,14,15,11)(10,12,16,13)(17,19,20,23)(18,22,21,24)(25,28,29,27)(26,32,30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.