One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,5)(7,8)(10,13)(11,15)(17,18,20,21)(19,22,23,24)(25,26)(27,29)(28,30)(31,32)(3,7)(6,8)(9,10)(11,16)(12,13)(14,15)(17,18)(19,22)(20,21)(23,24)(25,26,28,30)(27,31,32,29)(2,5)(6,8)(11,15)(14,16)(18,21)(19,23)(25,26)(27,31)(28,30)(29,32) involution — undirected(1,2)(3,6)(4,5)(7,8)(9,10)(11,14)(12,13)(15,16)(17,18)(19,22)(20,21)(23,24) involution — undirected(1,3,4,7)(2,6,5,8)(9,11)(10,14)(12,15)(13,16)(17,19,20,23)(18,22,21,24)(25,27)(26,29)(28,32)(30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.