One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,4,7,8)(9,10,13,14)(11,12,16,15)(17,18,21,22)(19,23,24,20)(2,6)(3,7)(10,14)(12,15)(18,22)(19,24)(25,26,28,30)(27,29,31,32)(9,11)(10,15)(12,14)(13,16)(17,19,21,24)(18,23,22,20)(25,26)(27,29)(28,30)(31,32)(1,3)(2,4)(5,7)(6,8)(9,12,13,15)(10,11,14,16)(17,18)(19,23)(20,24)(21,22)(1,4)(2,3)(5,8)(6,7)(9,11)(10,15)(12,14)(13,16)(17,20,21,23)(18,24,22,19)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.