One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,10)(3,11,15,25)(4,8,16,22)(5,18,12,9)(7,19,21,14)(13,24,27,32)(17,29,26,23)(20,30,31,28)(33,34)(35,40)(36,48)(37,42)(38,52)(39,43)(41,50)(44,57)(45,54)(46,55)(47,61)(49,56)(51,62)(53,60)(58,64)(59,63)(1,3,12,19,6,15,5,14)(2,7,18,25,10,21,9,11)(4,13,26,30,16,27,17,28)(8,20,29,32,22,31,23,24)(33,35)(34,40)(36,44)(37,46)(38,47)(39,45)(41,53)(42,55)(43,54)(48,57)(49,59)(50,60)(51,58)(52,61)(56,63)(62,64)(33,36,37,49,39,51,38,50)(34,41,52,62,43,56,42,48)(35,44,46,59,45,58,47,60)(40,53,61,64,54,63,55,57)(1,4)(2,8)(3,13)(5,17)(6,16)(7,20)(9,23)(10,22)(11,24)(12,26)(14,28)(15,27)(18,29)(19,30)(21,31)(25,32)(35,45)(40,54)(44,58)(46,47)(53,63)(55,61)(57,64)(59,60) involution — undirected(4,16)(8,22)(13,27)(17,26)(20,31)(23,29)(24,32)(28,30)(33,37,39,38)(34,42,43,52)(35,46,45,47)(36,49,51,50)(40,55,54,61)(41,48,56,62)(44,59,58,60)(53,57,63,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.