One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,6)(3,7,8,5)(9,10,14,12)(11,16,15,13)(18,22)(19,24)(1,3)(2,5)(4,8)(6,7)(9,11)(10,13)(12,16)(14,15)(25,26,28,30)(27,29,31,32)(2,6)(5,7)(10,12)(11,15)(17,18,21,22)(19,23,24,20)(25,26)(27,29)(28,30)(31,32)(1,2)(3,5)(4,6)(7,8)(9,12,14,10)(11,16,15,13)(17,19)(18,23)(20,22)(21,24)(1,3)(2,5)(4,8)(6,7)(9,13,14,16)(10,15,12,11)(17,20,21,23)(18,19,22,24)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.