One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,5)(7,8)(9,10,12,13)(11,14,15,16)(2,5)(6,8)(17,18,22,26)(19,27,29,32)(20,25,21,23)(24,30,31,28)(1,3,4,7)(2,6,5,8)(10,13)(14,16)(18,23)(20,21)(24,27)(25,26)(28,30)(31,32)(9,11,12,15)(10,14,13,16)(17,19)(18,24)(20,28)(21,30)(22,29)(23,27)(25,32)(26,31)(17,20,22,21)(18,23,26,25)(19,28,29,30)(24,27,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.