One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,8)(4,7)(5,6)(9,10)(11,14)(12,15)(13,16)(17,18,20,25,21,24,28,22)(19,23,27,30,26,31,32,29)(2,6)(7,8)(9,11,14,10)(12,15,13,16)(18,22)(19,26)(20,28)(23,30)(24,25)(29,31)(1,3,5,4)(2,7,6,8)(10,11)(15,16)(17,19,21,26)(18,23,24,31)(20,27,28,32)(22,29,25,30)(9,12,14,13)(10,15,11,16)(17,19)(18,23)(20,27)(21,26)(22,29)(24,31)(25,30)(28,32)(1,4,5,3)(2,7,6,8)(9,13,14,12)(10,15,11,16)(18,24)(19,26)(22,25)(27,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.