One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,8)(3,7,4,6)(17,18)(19,27)(20,26)(21,24)(22,25)(23,28)(29,32)(30,31)(1,3,5,4)(2,6,8,7)(9,10)(11,14)(12,13)(15,16)(1,3,5,4)(2,7,8,6)(10,13)(14,16)(17,19)(18,23)(20,28)(21,30)(22,29)(24,27)(25,31)(26,32)(1,3,5,4)(2,7,8,6)(9,11)(10,14)(12,15)(13,16)(17,20,22,21)(18,24,25,26)(19,28,29,30)(23,27,31,32)(1,4,5,3)(2,6,8,7)(11,15)(14,16)(18,25)(23,31)(24,26)(27,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.