One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(17,18)(19,27)(20,24)(21,25)(22,30)(23,26)(28,32)(29,31)(9,10)(11,14)(12,13)(15,16)(17,19,21,29,23,28,22,24)(18,20,30,32,26,31,25,27)(2,5)(6,8)(10,13)(14,16)(17,20,23,31)(18,24,26,29)(19,25,28,30)(21,32,22,27)(1,3,4,7)(2,6,5,8)(9,11)(10,14)(12,15)(13,16)(19,28)(20,31)(24,29)(27,32)(11,15)(14,16)(17,21,23,22)(18,25,26,30)(19,29,28,24)(20,27,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.