One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,7)(4,8)(5,6)(17,18,23,25,22,20,21,26)(19,24,29,31,30,27,28,32)(2,6)(7,8)(9,10)(11,14)(12,13)(15,16)(17,19,22,30)(18,24,20,27)(21,28,23,29)(25,31,26,32)(1,3,5,4)(2,7,6,8)(10,13)(14,16)(17,20,22,18)(19,27,30,24)(21,26,23,25)(28,32,29,31)(1,4,5,3)(2,8,6,7)(9,11)(10,14)(12,15)(13,16)(17,21,22,23)(18,25,20,26)(19,28,30,29)(24,31,27,32)(11,15)(14,16)(17,21,22,23)(18,25,20,26)(19,29,30,28)(24,32,27,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.