One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,4,8)(17,18,22,27)(19,20,29,32)(21,25,30,26)(23,28,31,24)(2,6)(7,8)(9,10)(11,14)(12,13)(15,16)(17,19,21,24,22,29,30,28)(18,23,26,20,27,31,25,32)(1,3,5,4)(2,7,6,8)(10,13)(14,16)(17,20,30,23,22,32,21,31)(18,24,25,19,27,28,26,29)(1,4,5,3)(2,8,6,7)(9,11)(10,14)(12,15)(13,16)(17,21,22,30)(18,25,27,26)(19,28,29,24)(20,31,32,23)(11,15)(14,16)(17,21,22,30)(18,25,27,26)(19,24,29,28)(20,23,32,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.