One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,4,8)(17,18)(19,27)(20,22)(21,25)(23,26)(24,30)(28,31)(29,32)(2,6)(7,8)(9,10)(11,14)(12,13)(15,16)(17,19,21,29,23,28,22,30)(18,24,20,31,26,32,25,27)(1,3,5,4)(2,7,6,8)(10,13)(14,16)(17,20,22,18,23,25,21,26)(19,27,30,32,28,31,29,24)(1,4,5,3)(2,8,6,7)(9,11)(10,14)(12,15)(13,16)(19,28)(24,32)(27,31)(29,30)(11,15)(14,16)(17,21,23,22)(18,25,26,20)(19,29,28,30)(24,27,32,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.