One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,8)(3,7,4,6)(9,10)(11,14)(12,16)(13,15)(18,24)(19,28)(26,30)(27,32)(1,3,5,4)(2,6,8,7)(9,11,13,12)(10,14,15,16)(17,18,22,24)(19,29,28,31)(20,26,25,30)(21,27,23,32)(1,3,5,4)(2,7,8,6)(10,15)(14,16)(17,19,22,28)(18,25,24,20)(21,26,23,30)(27,31,32,29)(9,12,13,11)(10,16,15,14)(17,20)(18,26)(19,27)(21,31)(22,25)(23,29)(24,30)(28,32)(1,4,5,3)(2,6,8,7)(17,21)(18,24)(19,30)(22,23)(26,28)(29,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.