One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,7)(4,6)(5,8)(9,10,12,13)(11,14,15,16)(17,18,22,23)(19,24,30,28)(20,26,21,25)(27,31,29,32)(1,3)(2,5)(4,8)(6,7)(17,19,22,30)(18,24,23,28)(20,31,21,32)(25,27,26,29)(10,13)(14,16)(17,20,22,21)(18,25,23,26)(19,27,30,29)(24,32,28,31)(2,6)(5,7)(17,18,22,23)(19,28,30,24)(20,25,21,26)(27,31,29,32)(3,8)(5,7)(9,11,12,15)(10,14,13,16)(17,21,22,20)(18,26,23,25)(19,29,30,27)(24,31,28,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.