One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10,13,15)(11,14,12,16)(17,18,22,26)(19,23,29,32)(20,24,21,25)(27,30,28,31)(9,10)(11,16)(12,14)(13,15)(17,19,22,29)(18,23,26,32)(20,28,21,27)(24,31,25,30)(2,5)(6,8)(9,11,13,12)(10,14,15,16)(19,27)(20,21)(23,30)(24,25)(28,29)(31,32)(9,12,13,11)(10,14,15,16)(17,20,22,21)(18,24,26,25)(19,28,29,27)(23,31,32,30)(1,3,4,7)(2,6,5,8)(19,28)(20,21)(23,31)(24,25)(27,29)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.