One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,5)(7,8)(9,10,13,14)(11,15,16,12)(17,18,22,24)(19,20,21,23)(25,26)(27,30)(28,29)(31,32)(2,5)(6,8)(10,14)(12,15)(17,19,22,21)(18,20,24,23)(26,29)(27,31)(17,20,22,23)(18,19,24,21)(25,26)(27,30)(28,29)(31,32)(1,3,4,7)(2,6,5,8)(9,11)(10,12)(13,16)(14,15)(17,18)(19,20)(21,23)(22,24)(1,2)(3,6)(4,5)(7,8)(9,12)(10,11)(13,15)(14,16)(17,21,22,19)(18,23,24,20)(25,27,28,31)(26,30,29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.