One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,6)(3,7,8,5)(17,18)(19,24)(20,28)(21,25)(22,27)(23,26)(29,30)(31,32)(1,3)(2,5)(4,8)(6,7)(9,10)(11,14)(12,13)(15,16)(17,19,23,29)(18,24,26,30)(20,25,31,27)(21,32,22,28)(3,8)(5,7)(10,13)(14,16)(17,20,21,30,23,31,22,24)(18,19,27,32,26,29,25,28)(2,6)(5,7)(9,11,12,15)(10,14,13,16)(17,21,23,22)(18,25,26,27)(19,28,29,32)(20,30,31,24)(10,13)(14,16)(17,21,23,22)(18,25,26,27)(19,28,29,32)(20,30,31,24)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.