One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10,12,14)(11,15,16,13)(19,25)(24,30)(26,31)(29,32)(9,11)(10,13)(12,16)(14,15)(18,22)(19,26)(20,27)(23,28)(24,30)(25,31) involution — undirected(2,5)(6,8)(10,14)(11,16)(17,18,20,22,21,23,27,28)(19,24,26,29,25,30,31,32)(10,14)(13,15)(18,23)(22,28)(24,30)(29,32) involution — undirected(1,3,4,7)(2,6,5,8)(17,19,27,31,21,25,20,26)(18,24,28,32,23,30,22,29)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.