One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10,13,15)(11,16,12,14)(9,10)(11,14)(12,16)(13,15)(17,18,22,27)(19,25,30,32)(20,24,28,26)(21,31,29,23)(2,5)(6,8)(9,11,13,12)(10,14,15,16)(17,19,28,21,22,30,20,29)(18,23,24,32,27,31,26,25)(9,11,13,12)(10,14,15,16)(17,20,22,28)(18,24,27,26)(19,21,30,29)(23,25,31,32)(1,3,4,7)(2,6,5,8)(9,12,13,11)(10,14,15,16)(17,21,28,30,22,29,20,19)(18,25,24,23,27,32,26,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.