One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,5)(7,8)(17,18,22,25)(19,26,29,32)(20,24,21,30)(23,27,31,28)(1,3,7,4)(2,5,8,6)(9,10)(11,15)(12,14)(13,16)(1,4,7,3)(2,5,8,6)(9,11)(10,13)(12,16)(14,15)(17,19,21,28,22,29,20,27)(18,23,24,26,25,31,30,32)(1,5,7,6)(2,3,8,4)(11,16)(13,15)(1,6,7,5)(2,3,8,4)(10,14)(13,15)(17,20,22,21)(18,24,25,30)(19,27,29,28)(23,26,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.