One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,6,8,7)(9,10)(11,16)(12,14)(13,15)(19,23)(21,24)(25,26,28,30)(27,29,31,32)(2,4)(6,7)(9,10,14,12)(11,15,13,16)(1,2,5,4)(3,7,8,6)(9,11,14,13)(10,15,12,16)(17,18,20,22)(19,21,23,24)(25,26)(27,29)(28,30)(31,32)(1,3,5,8)(2,6,4,7)(9,12,14,10)(11,15,13,16)(17,19)(18,21)(20,23)(22,24)(25,27,28,31)(26,29,30,32)(1,4,5,2)(3,7,8,6)(9,13,14,11)(10,15,12,16)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.