One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,5)(4,6)(7,8)(9,10)(11,12)(13,15)(14,16)(17,18,21,22)(19,23,24,20)(25,26,29,28)(27,30,31,32)(1,3)(2,7)(4,5)(6,8)(9,11,13,16)(10,14,15,12)(18,22)(20,23)(27,31)(30,32)(2,4)(3,8)(11,16)(12,14)(17,19,21,24)(18,20,22,23)(25,27)(26,30)(28,32)(29,31)(1,4,6,2)(3,5,8,7)(9,12)(10,11)(13,14)(15,16)(17,19)(18,23)(20,22)(21,24)(25,26,29,28)(27,30,31,32)(1,5)(2,3)(4,8)(6,7)(9,10)(11,12)(13,15)(14,16)(17,20,21,23)(18,19,22,24)(25,28,29,26)(27,32,31,30)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.