One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,9)(3,10,13,7)(4,8,5,14)(11,16,12,15)(17,18)(19,22)(20,27)(21,23)(24,29)(25,31)(26,32)(28,30)(33,34)(35,44)(36,41)(37,42)(38,53)(39,43)(40,47)(45,60)(46,55)(48,61)(49,64)(50,57)(51,59)(52,58)(54,62)(56,63)(1,3,6,13)(2,7,9,10)(4,11,5,12)(8,15,14,16)(17,19)(18,22)(20,28)(21,25)(23,31)(24,32)(26,29)(27,30)(1,4,6,5)(2,8,9,14)(3,11,13,12)(7,15,10,16)(18,23)(19,25)(24,27)(26,28)(33,35,38,47,39,48,37,46)(34,40,42,44,43,55,53,61)(36,49,50,63,51,45,52,62)(41,56,58,64,59,54,57,60)(1,4,6,5)(2,8,9,14)(3,12,13,11)(7,16,10,15)(17,20,21,29)(18,24,23,27)(19,26,25,28)(22,30,31,32)(33,36,39,51)(34,41,43,59)(35,45,48,49)(37,52,38,50)(40,54,55,56)(42,58,53,57)(44,60,61,64)(46,63,47,62)(1,5,6,4)(2,8,9,14)(3,12,13,11)(7,15,10,16)(19,25)(22,31)(26,28)(30,32)(33,37,39,38)(34,42,43,53)(35,46,48,47)(36,50,51,52)(40,44,55,61)(41,57,59,58)(45,62,49,63)(54,64,56,60)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.