One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,9)(3,10,13,7)(4,8,5,14)(11,16,12,15)(17,18)(19,22)(20,27)(21,23)(24,29)(25,31)(26,32)(28,30)(33,34)(35,43)(36,41)(37,53)(38,39)(40,48)(42,44)(45,61)(46,54)(47,57)(49,55)(50,64)(51,60)(52,59)(56,62)(58,63)(1,3,6,13)(2,7,9,10)(4,11,5,12)(8,15,14,16)(17,19)(18,22)(20,28)(21,25)(23,31)(24,32)(26,29)(27,30)(34,39)(36,49)(40,54)(42,53)(43,57)(45,50)(51,52)(62,63)(1,4,6,5)(2,8,9,14)(3,11,13,12)(7,15,10,16)(18,23)(19,25)(24,27)(26,28)(33,35,44,46,38,47,37,48)(34,40,53,57,39,54,42,43)(36,50,51,62,49,45,52,63)(41,58,59,61,55,56,60,64)(1,4,6,5)(2,8,9,14)(3,12,13,11)(7,16,10,15)(17,20,21,29)(18,24,23,27)(19,26,25,28)(22,30,31,32)(33,36)(34,41)(35,45)(37,52)(38,49)(39,55)(40,56)(42,60)(43,61)(44,51)(46,63)(47,50)(48,62)(53,59)(54,58)(57,64)(1,5,6,4)(2,8,9,14)(3,12,13,11)(7,15,10,16)(19,25)(22,31)(26,28)(30,32)(33,37,38,44)(34,42,39,53)(35,46,47,48)(36,51,49,52)(40,57,54,43)(41,59,55,60)(45,62,50,63)(56,61,58,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.