One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,8,4)(9,10,13,12)(11,14,16,15)(19,23)(22,24)(2,6)(4,7)(10,12)(14,15)(18,21)(22,24)(25,26,28,30)(27,29,31,32)(1,3,5,8)(2,4,6,7)(9,10,13,12)(11,15,16,14)(17,18)(19,22)(20,21)(23,24)(25,26)(27,29)(28,30)(31,32)(1,3)(2,7)(4,6)(5,8)(9,11,13,16)(10,14,12,15)(17,19)(18,22)(20,23)(21,24)(25,27,28,31)(26,29,30,32)(1,4,5,7)(2,3,6,8)(9,12,13,10)(11,15,16,14)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.