One vertex per element, one color per generator, with an edge from x to x·s.
(9,10,14,16)(11,12,15,13)(17,18,21,22)(19,25,26,32)(20,29,30,24)(23,27,31,28)(1,2)(3,7)(4,6)(5,8)(9,11,14,15)(10,13,16,12)(18,22)(19,26)(24,29)(27,28)(1,3)(2,5)(4,8)(6,7)(9,10)(11,12)(13,15)(14,16)(17,19,20,28,21,26,30,27)(18,23,24,25,22,31,29,32)(2,6)(3,8)(9,12,14,13)(10,15,16,11)(2,6)(5,7)(9,13,14,12)(10,15,16,11)(17,20,21,30)(18,24,22,29)(19,27,26,28)(23,32,31,25)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.