One vertex per element, one color per generator, with an edge from x to x·s.
(9,10,14,16)(11,12,15,13)(18,22)(20,24)(23,28)(25,29)(27,31)(30,32)(1,2)(3,7)(4,6)(5,8)(9,11,14,15)(10,13,16,12)(18,23)(19,26)(22,28)(27,31)(1,3)(2,5)(4,8)(6,7)(9,10)(11,12)(13,15)(14,16)(17,18,24,28,21,23,20,22)(19,25,31,32,26,30,27,29)(2,6)(3,8)(9,12,14,13)(10,15,16,11)(17,19,21,26)(18,25,23,30)(20,27,24,31)(22,29,28,32)(2,6)(5,7)(9,13,14,12)(10,15,16,11)(18,23)(19,26)(22,28)(27,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.