One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,5)(3,8,4,7)(9,10)(11,13)(12,14)(15,16)(18,21)(22,24)(26,30)(31,32)(1,3,6,4)(2,7,5,8)(9,10,12,14)(11,13,15,16)(3,4)(7,8)(11,15)(13,16)(17,18)(19,22)(20,21)(23,24)(25,26,29,30)(27,31,28,32)(1,4,6,3)(2,7,5,8)(9,11,12,15)(10,13,14,16)(17,18)(19,22)(20,21)(23,24)(25,27,29,28)(26,31,30,32)(1,5,6,2)(3,7,4,8)(9,10)(11,13)(12,14)(15,16)(17,19,20,23)(18,22,21,24)(25,28,29,27)(26,32,30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.