One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,4,8)(9,10)(11,15)(12,14)(13,16)(17,18)(19,22)(20,28)(21,25)(23,27)(24,29)(26,30)(31,32)(2,6)(7,8)(11,16)(13,15)(17,19,21,27)(18,23,25,22)(20,24,29,28)(26,31,32,30)(1,3,5,4)(2,7,6,8)(9,11,12,16)(10,13,14,15)(17,19)(18,23)(20,26)(21,27)(22,25)(24,30)(28,31)(29,32)(10,14)(13,15)(17,20,21,29)(18,24,25,28)(19,26,27,32)(22,31,23,30)(1,4,5,3)(2,7,6,8)(18,25)(19,27)(24,28)(26,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.