One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,7)(4,8)(5,6)(9,10,12,14)(11,15,16,13)(17,18,22,25)(19,21,27,23)(20,24,29,32)(26,30,31,28)(2,6)(7,8)(9,11,12,16)(10,13,14,15)(17,19)(18,23)(20,24)(21,25)(22,27)(26,30)(28,31)(29,32)(1,3,5,4)(2,7,6,8)(10,14)(11,16)(17,19)(18,21)(20,26)(22,27)(23,25)(24,30)(28,32)(29,31)(1,4,5,3)(2,8,6,7)(10,14)(13,15)(17,20)(18,24)(19,26)(21,30)(22,29)(23,28)(25,32)(27,31)(2,6)(7,8)(10,14)(13,15)(17,21,22,23)(18,19,25,27)(20,28,29,30)(24,31,32,26)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.