One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10)(11,16)(12,15)(13,14)(17,18)(19,23)(20,28)(21,27)(22,25)(24,31)(26,30)(29,32)(2,5)(6,8)(9,10)(11,16)(12,15)(13,14)(17,19,22,27)(18,21,25,23)(20,24,31,28)(26,32,29,30)(1,3,4,7)(2,6,5,8)(10,14)(15,16)(17,19)(18,21)(20,29)(22,27)(23,25)(24,32)(26,31)(28,30)(9,11,13,12)(10,15,14,16)(17,20)(18,24)(19,26)(21,30)(22,31)(23,32)(25,28)(27,29)(2,5)(6,8)(9,12,13,11)(10,15,14,16)(17,21,22,23)(18,19,25,27)(20,30,31,32)(24,26,28,29)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.