One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10)(11,16)(12,15)(13,14)(18,22)(23,31)(24,29)(25,32)(2,5)(6,8)(9,10)(11,16)(12,15)(13,14)(17,18,20,22)(19,25,26,32)(21,29,28,24)(23,30,31,27)(1,3,4,7)(2,6,5,8)(10,14)(15,16)(19,26)(23,31)(25,32)(27,30)(9,11,13,12)(10,15,14,16)(17,19)(18,23)(20,26)(21,30)(22,31)(24,32)(25,29)(27,28)(2,5)(6,8)(9,12,13,11)(10,15,14,16)(19,26)(23,31)(25,32)(27,30)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.