One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,7,4,8)(9,10,12,14)(11,13,15,16)(18,24)(19,29)(20,31)(21,23)(25,32)(26,30)(2,6)(7,8)(9,11)(10,13)(12,15)(14,16)(17,18,22,24)(19,20,30,32)(21,27,23,28)(25,26,31,29)(1,3,5,4)(2,7,6,8)(17,19,23,29,22,30,21,26)(18,25,27,20,24,31,28,32)(1,3,5,4)(2,7,6,8)(11,15)(13,16)(17,20,21,25,22,32,23,31)(18,26,28,30,24,29,27,19)(1,4,5,3)(2,7,6,8)(17,21,22,23)(18,27,24,28)(19,26,30,29)(20,31,32,25)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.