One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,4)(3,7,5,8)(9,10,12,14)(11,13,15,16)(17,18,23,25)(19,22,28,24)(20,26,29,31)(21,27,30,32)(1,3,6,5)(2,7,4,8)(9,10)(11,13)(12,14)(15,16)(17,19,23,28)(18,24,25,22)(20,21,29,30)(26,32,31,27)(2,4)(7,8)(9,11,12,15)(10,13,14,16)(18,25)(19,28)(20,29)(27,32)(1,4,6,2)(3,8,5,7)(17,20,23,29)(18,26,25,31)(19,21,28,30)(22,27,24,32)(1,5,6,3)(2,8,4,7)(17,21)(18,27)(19,29)(20,28)(22,31)(23,30)(24,26)(25,32)(17,22,23,24)(18,28,25,19)(20,27,29,32)(21,26,30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.