One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,7,8,6)(9,10)(11,12)(13,16)(14,15)(17,18,22,23)(19,27,28,24)(20,25,30,29)(21,26,31,32)(1,3,5,8)(2,6,4,7)(9,11,14,13)(10,12,15,16)(17,18)(19,24)(20,25)(21,26)(22,23)(27,28)(29,30)(31,32)(1,2,5,4)(3,6,8,7)(10,15)(12,16)(18,23)(19,28)(25,29)(26,32)(9,12,14,16)(10,11,15,13)(17,19,22,28)(18,24,23,27)(20,26,30,32)(21,29,31,25)(9,13,14,11)(10,16,15,12)(17,20)(18,25)(19,26)(21,24)(22,30)(23,29)(27,31)(28,32)(1,4,5,2)(3,7,8,6)(17,21)(18,26)(19,29)(20,27)(22,31)(23,32)(24,30)(25,28)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.