One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,4)(3,8,5,7)(9,10)(11,15)(12,14)(13,16)(17,18,23,20)(19,24,22,26)(21,25,30,28)(27,31,29,32)(1,3,6,5)(2,7,4,8)(17,19,23,22)(18,24,20,26)(21,27,30,29)(25,31,28,32)(2,4)(7,8)(9,10,12,14)(11,13,16,15)(19,22)(24,26)(27,29)(31,32)(1,4,6,2)(3,8,5,7)(9,10)(11,13)(12,14)(15,16)(17,20,23,18)(19,26,22,24)(21,25,30,28)(27,31,29,32)(1,5,6,3)(2,8,4,7)(9,11)(10,13)(12,16)(14,15)(17,21)(18,25)(19,27)(20,28)(22,29)(23,30)(24,31)(26,32)(17,22,23,19)(18,26,20,24)(21,29,30,27)(25,32,28,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.