One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,5)(3,8,4,7)(9,10)(11,16)(12,15)(13,14)(17,18,22,24)(19,20,21,23)(25,26,28,30)(27,29,31,32)(1,3,6,4)(2,7,5,8)(10,14)(15,16)(17,19,22,21)(18,23,24,20)(25,26,28,30)(27,29,31,32)(9,11,13,12)(10,15,14,16)(17,20)(18,19)(21,24)(22,23)(25,26)(27,29)(28,30)(31,32)(1,4,6,3)(2,8,5,7)(9,12,13,11)(10,15,14,16)(17,21,22,19)(18,20,24,23)(1,5,6,2)(3,7,4,8)(9,10)(11,15)(12,16)(13,14)(17,20)(18,21)(19,24)(22,23)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.