One vertex per element, one color per generator, with an edge from x to x·s.
(9,10,14,16)(11,13,15,12)(18,23)(19,26)(25,32)(27,29)(1,2)(3,8)(4,6)(5,7)(9,11)(10,13)(12,16)(14,15)(17,18,22,23)(19,24,26,20)(21,25,31,32)(27,30,29,28)(1,3,5,4)(2,6,7,8)(9,12,14,13)(10,15,16,11)(1,2)(3,6)(4,8)(5,7)(9,10,14,16)(11,12,15,13)(17,19)(18,24)(20,23)(21,29)(22,26)(25,28)(27,31)(30,32)(1,2)(3,6)(4,8)(5,7)(9,11)(10,12)(13,16)(14,15)(17,20,22,24)(18,19,23,26)(21,30,31,28)(25,29,32,27)(1,4,5,3)(2,6,7,8)(9,13,14,12)(10,15,16,11)(17,21,22,31)(18,25,23,32)(19,27,26,29)(20,28,24,30)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.