One vertex per element, one color per generator, with an edge from x to x·s.
(2,4)(6,8)(9,10,13,14)(11,16,15,12)(17,18)(19,23)(20,22)(21,24)(27,31)(29,32)(1,2,5,4)(3,6,7,8)(9,10)(11,16)(12,15)(13,14)(17,18,20,22)(19,21,24,23)(3,7)(6,8)(10,14)(11,15)(17,18,20,22)(19,21,24,23)(25,26,28,30)(27,29,31,32)(1,3)(2,6)(4,8)(5,7)(9,11,13,15)(10,12,14,16)(17,18)(19,21)(20,22)(23,24)(25,27)(26,29)(28,31)(30,32)(1,4,5,2)(3,8,7,6)(9,12)(10,15)(11,14)(13,16)(17,19)(18,21)(20,24)(22,23)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.