One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,7)(4,5)(6,8)(9,10,13,11)(12,15,16,14)(18,20)(19,21)(25,26,28,30)(27,29,31,32)(2,5)(6,7)(9,10)(11,13)(12,14)(15,16)(17,18)(19,24)(20,22)(21,23)(25,27,28,31)(26,29,30,32)(2,5)(6,7)(10,11)(14,15)(17,19,22,21)(18,23,20,24)(25,26)(27,29)(28,30)(31,32)(1,2)(3,6)(4,5)(7,8)(9,11,13,10)(12,15,16,14)(17,20,22,18)(19,23,21,24)(25,27)(26,29)(28,31)(30,32)(1,3,4,8)(2,6,5,7)(9,12,13,16)(10,14,11,15)(17,21,22,19)(18,23,20,24)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.